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槐花炭化学成分的研究
引用本文:李娆娆,原思通,李志宏,秦海林. 槐花炭化学成分的研究[J]. 中国中药杂志, 2005, 30(16): 1255-1257
作者姓名:李娆娆  原思通  李志宏  秦海林
作者单位:1. 中国中医研究院,中药研究所,北京,100700;中国医学科学院,中国协和医科大学,药物研究所,北京,100050
2. 中国中医研究院,中药研究所,北京,100700
3. 中国医学科学院,中国协和医科大学,药物研究所,北京,100050
摘    要:目的:研究中药槐花炭的化学成分。方法:用硅胶柱色谱法和光谱分析法分离和鉴定化学成分。结果:分得6个化合物,经光谱分析鉴定其结构分别为麦芽酚(1),3-羟基吡啶(2),麦芽酚-3-氧-[6′-氧-(4″-羟基-反式-桂皮酰基)]-β-D-吡喃葡萄糖苷(3),3-氧-[β-D-半乳吡喃糖基-(1→2)-p-β-葡萄吡喃醛酸糖基]槐二醇乙酯(4),3-氧-[β-D-半乳吡喃糖基.(1→2)-β-D-葡萄吡喃醛酸糖基]槐二醇甲酯(5),芦丁(6)。结论:化合物4为新化合物,化合物1,2,3,5为首次从槐花炭中获得。

关 键 词:槐花炭  麦芽酚衍生物  三萜皂苷
文章编号:1001-5302(2005)16-1255-03
收稿时间:2004-05-10
修稿时间:2004-05-10

Studies on chemical constituents in Flos Sophorae Carbonisatus
LI Rao-rao;YUAN Si-tong;LJ Zhi-hong;QIN Hai-lin. Studies on chemical constituents in Flos Sophorae Carbonisatus[J]. China Journal of Chinese Materia Medica, 2005, 30(16): 1255-1257
Authors:LI Rao-rao  YUAN Si-tong  LJ Zhi-hong  QIN Hai-lin
Affiliation:Institute of Chinese Materia Medica, China Academy of Traditional Chinese Medicine, Beijing 100700, China.
Abstract:OBJECTIVE: To investigate the chemical constituents in Flos Sophorae Carbonisatus. METHOD: Silica gel column chromatography was used to separate and purify the chemical constituents. The structures were elucidated by spectral analysis. RESULT: Six compounds were isolated from Flos Sophorae Carbionisatus, and their structures were elucidated as maltol (1), 3-hydroxypyridine (2), malto-3-O-[6'-O-(4"-hydroxy-tans-cinnamoyl)-beta-D-glucopyranoside (3), 3-O-[beta-D-galactopyranosyl-(1-->2)-beta-D-glucuronopyranosyl] sophoradiol ethyl ester (4), 3-O-[beta-D-galactopyranosyl-(1-->2)-beta-D-glucuronopyranosyl] sophoradiol methyl ester (5), rutin (6). CONCLUSION: 4 is a new compound, and 1,2,3,5 were first reported from Flos Sophorae Carbonisatus.
Keywords:Hos Sophorae Carbonisatus  saponins  maltol derivatives
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