|
|||||
|
|
Voltammetric investigation of diethylstilbestrol |
|
| Authors: | Biryol Inci Salci Bülent Erdik Ender |
| Affiliation: | a Department of Analytical Chemistry, Faculty of Pharmacy, Ankara University, 06 100, Ankara, Turkey b Ministry of Agriculture P. K. 36, Yenimahalle, 06 170, Ankara, Turkey c Department of Chemistry, Faculty of Science, Ankara University, 06 100, Ankara, Turkey |
| Abstract: | In this work electrooxidation of diethylstilbestrol (DES) was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) using a glassy carbon (GC) electrode. It was statistically shown that both methods could be used for the determination of DES in the concentration range of 2×10−5–6×10−4 M by CV and 1×10−5–1×10−3 M in methanol (MeOH) and 4×10−5–6×10−4 M in acetonitrile (ACN) by DPV and both of the methods could be applied to human serum. A mechanism was proposed about the electrooxidation of this substance. |
| Keywords: | Diethylstilbestrol Electrooxidation Cyclic voltammetry Differential pulse voltammetry Determination |
| 本文献已被 ScienceDirect PubMed 等数据库收录！ | |