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催化动力学光度法测定痕量铁的研究
引用本文:高金波,侯巍,丁立新. 催化动力学光度法测定痕量铁的研究[J]. 微量元素与健康研究, 2003, 20(1): 43-45
作者姓名:高金波  侯巍  丁立新
作者单位:佳木斯大学化学与药学院,黑龙江,佳木斯,154007
摘    要:研究了在硫酸介质中 ,铁催化过氧化氢氧化罗丹明B的褪色反应及动力学条件 ,建立了高灵敏测定痕量铁的新方法。线性范围 :0 0 0~ 0 80 μg/ 2 5ml;检出限 :0 2× 10 -9;RSD =2 1%。应用于人发、粮食、分析纯盐酸中痕量铁的测定 ,结果令人满意

关 键 词:罗丹明B    催化动力学光度法
文章编号:1005-5320(2003)01-0043-03
修稿时间:2002-10-13

Determination of Trace iron with cacalytic kinetic spectrophotometry
Gao Jin-bo,Hou Wei,Ding Li-xin. Determination of Trace iron with cacalytic kinetic spectrophotometry[J]. Studies of Trace Elements and Health, 2003, 20(1): 43-45
Authors:Gao Jin-bo  Hou Wei  Ding Li-xin
Abstract:A new catalytic kinetic spectrophotometry method for the determination of trace iron is described.The method is based on the catalytic of rhodamine B with hydrogen peroxide in hydrochloric acid medium.The method has high sensitivity and selectivity for determining trace iron.The linear range of the determination is 0.00~0.80 μg/25 ml and the detection limit for iron is 0.2×10 -9 .RSD=2.1.The method has been used to determine trace iron in human hair gramn,hydrochloric acid used by analysis with satisfactory results
Keywords:rhodamine B  iron  catalytic kinetic spectphotometry
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