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Re-Melting Behaviour and Wear Resistance of Vanadium Carbide Precipitating Cr27.5Co14Fe22Mo22Ni11.65V2.85 High Entropy Alloy
Authors:Kai Treutler  Swenja Lorenz  Volker Wesling
Institution:Institute of Welding and Machining, Clausthal University of Technology, 38678 Clausthal-Zellerfeld, Germany; (S.L.); (V.W.)
Abstract:High entropy alloys (HEAs) are among of the most promising new metal material groups. The achievable properties can exceed those of common alloys in different ways. Due to the mixture of five or more alloying elements, the variety of high entropy alloys is fairly huge. The presented work will focus on some first insights on the weldability and the wear behavior of vanadium carbide precipitation Cr27.5Co14Fe22Mo22Ni11.65V2.85 HEA. The weldability should always be addressed in an early stage of any alloy design to avoid welding-related problems afterwards. The cast Cr27.5Co14Fe22Mo22Ni11.65V2.85 HEA has been remelted using a TIG welding process and the resulting microstructure has been examined. The changes in the microstructure due to the remelting process showed little influence of the welding process and no welding-related problems like hot cracks have been observed. It will be shown that vanadium carbides or vanadium-rich phases precipitate after casting and remelting in a two phased HEA matrix. The hardness of the as cast alloy is 324HV0.2 and after remelting the hardness rises to 339HV0.2. The wear behavior can be considered as comparable to a Stellite 6 cobalt base alloy as determined in an ASTM G75 test. Overall, the basic HEA design is promising due to the precipitation of vanadium carbides and should be further investigated.
Keywords:high entropy alloy (HEA)  wear  weldability  microstructure  ASTM G75  precipitating  vanadium carbide
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