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Simultaneous assessment of zinc,cadmium, lead and copper in poultry feeds by differential pulse anodic stripping voltammetry
Authors:SA Mahesar  STH Sherazi  Abdul Niaz  MI Bhanger  Siraj uddin  Abdul Rauf
Institution:1. RUSA-Center for Advanced Sensor Technology, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431 004, (MS) India;2. Department of Physical Chemistry, Faculty of Chemistry and Geosciences, Vilnius University, Naugarduko St. 24, LT-03225 Vilnius, Lithuania;3. Laboratory of Bioelectrochemistry, State Research Institute Center for Physical Sciences and Technology, Sauletekio Ave 3, LT-10257 Vilnius, Lithuania;4. NanoTechnas – Centre of Nanotechnology and Material Science, Faculty of Chemistry and Geosciences, Vilnius University, Naugarduko St. 24, LT-03225 Vilnius, Lithuania;5. Laboratory of Nanotechnology, State Research Institute Center for Physical Sciences and Technology, Sauletekio Ave 3, LT-10257 Vilnius, Lithuania;1. Shandong University of Technology, Zibo 255049, PR China;2. Key Lab of Modern Precision Agriculture System Integration Research, Ministry of Education of China, China Agricultural University, Beijing 100083, PR China;3. Key Lab of Agricultural Information Acquisition Technology, Ministry of Agricultural of China, China Agricultural University, Beijing 100083, PR China;1. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India;2. Sinop University, Faculty of Arts and Science, Department of Chemistry, Sinop, Turkey;3. Hacettepe University, Faculty of Pharmacy, Department of Analytical Chemistry, Ankara, Turkey;4. Dumlupinar University, Faculty of Arts and Science, Department of Chemistry, Kutahya, Turkey;5. Ankara University, Faculty of Science, Department of Chemistry, Ankara, Turkey;6. Kyrgyz-Turk Manas University, Faculty of Engineering, Department of Chemical Engineering, Bishkek, Kyrgyzstan;1. Department of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China;2. Harbin Institute of Technology, Shenzhen Graduate School, Shenzhen 518055, China;1. Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China;2. Soil and Water Quality Laboratory, Gulf Coast Research and Education Center, University of Florida, Wimauma 33598, FL, USA;3. Taicang Soil Management Station, Taicang 215400, China
Abstract:In the present work four metals (Zn, Cd, Pb and Cu) were determined simultaneously in 28 commercial broiler poultry feeds by differential pulse anodic stripping voltammetry (DPASV) using hanging mercury drop electrode (HMDE). The digestion of poultry feeds was carried out with concentrated nitric acid and hydrogen peroxide (2:1) with the help of microwave heating. Acetate buffer of pH 5 was used as a supporting electrolyte. The limit of detection for Zn, Cd, Pb and Cu was 0.69, 0.35, 0.68 and 0.24 μg/kg, respectively. The amount of Zn, Cd, Pb and Cu in the analyzed poultry feeds was ranged between 54.3–482.2, 3.8–33.6, 23.2–32.6 and 12.3–65.8 mg/kg, respectively. In most of analyzed poultry feed samples, the amount of Cd and Pb was found to be greater than the maximum tolerable level (MTL) which could be harmful for the poultry.
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