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结晶驱动自组装的研究进展
引用本文:杨纤,冯纯,陆国林,黄晓宇. 结晶驱动自组装的研究进展[J]. 医学教育探索, 2017, 30(1): 15-33
作者姓名:杨纤  冯纯  陆国林  黄晓宇
作者单位:中国科学院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室, 上海 200032,中国科学院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室, 上海 200032,中国科学院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室, 上海 200032,中国科学院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室, 上海 200032
基金项目:国家自然科学基金(21474127,51373196,21504102)
摘    要:在两亲性聚合物的自组装领域,结晶驱动自组装因其内容的丰富性和较高的可塑性而被特殊看待。在经典的自组装体系中,要制备纤维状胶束相对比较困难,而结晶驱动自组装却能够很轻易地得到纤维状胶束并实现纤维的组成、长度及长度分布控制。其中,可结晶嵌段的结晶性被认为是形成纤维状胶束的关键并被进一步跟进拓展。

关 键 词:自组装  纤维状胶束  结晶性  纳米结构
收稿时间:2017-01-18

Advances in Crystallization-Driven Self-Assembly
YANG Xian,FENG Chun,LU Guo-lin and HUANG Xiao-yu. Advances in Crystallization-Driven Self-Assembly[J]. Researches in Medical Education, 2017, 30(1): 15-33
Authors:YANG Xian  FENG Chun  LU Guo-lin  HUANG Xiao-yu
Affiliation:Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China,Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China,Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China and Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Abstract:In the field of self-assembly of amphiphilic polymers,crystallization-driven self-assembly draws special attentions because of its richness in content and high mold ability.Cylindrical micelles with controllable compositions,length and distribution,which are difficult to obtain in conventional self-assembly systems,are highly available using crystallization-driven self-assembly.The crystallinity in copolymers is considered the key to the formation of cylindrical micelles and is widely studied.
Keywords:self-assembly  cylindrical micelles  crystallinity  nanostructures
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