| 国槐尺蠖昆虫信息素组份的全合成新法（Ⅰ） |
| |
| 引用本文： | 龚考才 黄瑜. 国槐尺蠖昆虫信息素组份的全合成新法（Ⅰ）[J]. 泸州医学院学报, 2000, 23(1): 6-9 |
| |
| 作者姓名： | 龚考才 黄瑜 |
| |
| 作者单位： | 泸州医学院有机化学教研室!646000(龚考才，刘林，杜军，杜曦)，中国科学院成都生物研究所(黄瑜，于源) |
| |
| 摘 要： | 目的：合成国槐尺蠖昆虫信息素两种组份（３Ｚ，６Ｚ，９Ｚ－３，６，９－十七碳三烯（０７）和（３Ｚ，６Ｚ，９Ｚ）－３，６，９－十八碳三烯（０９）。方法：Ｃｕ（Ｉ）相转移条件下，以丙炔醇为基本原料，末端炔的炳丙基化反应作为关键反应进行合成。结果：实现了主要组份０７和０９的全合成，收率良好，结论：合成新法解决了重排副反应问题，且新法具有区域选择性强，目标物收率高等优点。新法对进一步合成有关生物活性物质具
|
| 关 键 词： | 相转移催化 国槐尺蠖 昆虫信息素 合成 |
A NEW METHOD OF TOTAL SYNTHESIS OF SEX PHEROMONE COMPONENTS OF MACARIA ELONGARIA LEECH |
| |
| Gong Kaocai,et al. A NEW METHOD OF TOTAL SYNTHESIS OF SEX PHEROMONE COMPONENTS OF MACARIA ELONGARIA LEECH[J]. Journal of Luzhou Medical College, 2000, 23(1): 6-9 |
| |
| Authors: | Gong Kaocai et al |
| |
| Affiliation: | Gong Kaocai,et al Department of Organic Chemistry,Luzhou Medical College |
| |
| Abstract: | Objective:To synthesize two main coponents of sex pheromone of the Macaria Elongaria Leech (3Z,6Z,9Z)-3,6,9-heptadectriene(07)and (3Z,6Z,9Z)-3,6,9-Octadectriene(09).Methods:The two components were synthesized with propynol as the basic raw materials and with the propargyl reaction of terminalal kyne under phase transfer condition in the presenee of Cu(I) salt as the key step.Results:Two components of the pheromone (07 and 09)were totally synthsized in good yield.Conclusions:This new method was able to resolve the problem of secondary reaction of rearrangement had good choice and strong collections of aim objects.The mothod has important significance for further synthesis of other bioloical active substances. |
| |
| Keywords: | |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
