| 四苯基卟啉衍生物的光谱研究 |
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| 引用本文： | 陈建文,黄德音. 四苯基卟啉衍生物的光谱研究[J]. 医学教育探索, 1992, 0(2) |
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| 作者姓名： | 陈建文 黄德音 |
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| 作者单位： | 华东化工学院专用化学品研究所，华东化工学院专用化学品研究所 厦门福达感光材料有限公司研究所 |
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| 摘 要： | 用混合醛与吡咯缩合,合成了七种对称及不对称的中位硝基取代苯基卟啉及其还原产品:TPP(NO_2)_n,TPP(NH_2)_n[n=0,1,3,4)。研究了它们的吸收光谱,发现苯基上取代基对吸收光谱有较大的影响,而且所用溶剂的极性也会影响光谱的特性;此外,还对这些化合物的荧光光谱进行了测定并讨论。
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| 关 键 词： | 吡咯 卟啉 光催化 荧光光谱 四苯基卟啉 |
Study on the Spectra of Tetraphenylporphyrin Derivates |
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| Chen Jianwen Huang Deyin. Study on the Spectra of Tetraphenylporphyrin Derivates[J]. Researches in Medical Education, 1992, 0(2) |
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| Authors: | Chen Jianwen Huang Deyin |
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| Affiliation: | Research Institute of Speciality Chemicals |
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| Abstract: | Seven symmetric or unsymmetric substituted tetraphenylporphyrins TPP(NO_2)_n, TPP(NH_2)_n[n=0, 1, 3, 4]were prepared by condensation of mixed aldehydes with pyrrole. Their absorption spectra were studied. It was found, the spectra are evidently influenced by the substituents on phenyl groups, furthermore, solvents used could affect the characteristics of their absorption spectra. Fluorescence spectra of those compounds were also measured and discussed. |
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| Keywords: | pyrrole porphyrin photocatalysis teraphenylporphyrin fluorescence spectra |
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