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Mathematical modelling and numerical simulation of adsorption processes at microdisk electrodes
Authors:François G. Chevallier  Oleksiy V. Klymenko  Li Jiang  Timothy G.J. Jones  Richard G. Compton
Affiliation:1. Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford OX1 3QZ, UK;2. Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge CB3 OEL, UK
Abstract:A general mathematical model for electrosorption under planar and microdisk diffusion conditions has been developed and solved using numerical simulation. This model allowed us to explore the electrochemical behaviour of such systems and to highlight some of their main properties.
Keywords:Digital simulation  Adsorption  Microelectrodes  Cyclic voltammetry  Mass transport
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