| 国产沉香化学成分的研究 Ⅱ.白木香醇和去氢白木香醇的分离和结构 |
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| 引用本文： | 杨峻山,陈玉武.国产沉香化学成分的研究 Ⅱ.白木香醇和去氢白木香醇的分离和结构[J].药学学报,1986,21(7):516-520. |
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| 作者姓名： | 杨峻山 陈玉武 |
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| 作者单位： | 中国医学科学院药物研究所,北京 |
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| 摘 要： | 自国产沉香系瑞香料(Thymelaceae)植物白木香(Aquilaria slnensuis(Lour.)Gilg.)的含有黑色树脂的木质部]的挥发油中经硅胶柱层析和制备性薄层层析分离得到两个新的沉香呋喃类倍半萜,分别命名为白木香醇(baimuxinol)和去氢白木香醇(dehydrobaimuxinol)。经光谱IR,1H NMR,MS分析和化学方法,确定它们的结构分别为式(Ⅰ)和(Ⅱ)。
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| 关 键 词： | 国产沉香 瑞香料 白木香 挥发油 倍半萜 白木香醇 去氢白木香醇 |
| 收稿时间： | 1985-04-03 |
Studies on the chemical constituents of Aquilaria sinensis (Lour.) Gilg. II. Isolation and structure of baimuxinol and dehydrobaimuxinol |
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| YANG Jun-Shan and CHEN Yu-Wu.Studies on the chemical constituents of Aquilaria sinensis (Lour.) Gilg. II. Isolation and structure of baimuxinol and dehydrobaimuxinol[J].Acta Pharmaceutica Sinica,1986,21(7):516-520. |
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| Authors: | YANG Jun-Shan and CHEN Yu-Wu |
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| Abstract: | Two new sesquiterpenoids, baimuxinol C15)H26O2 mp 128～130℃,. α]D30-83°(c 0.56, CHCl3) and dehydrobaimuxinol C15H24O2 mp 136～138℃,α]D26+25°(c, 1.60, CHCl3), have been isolated from the volatile oil of Aquilaria sinensis (Lour). Gilg. (Thymelaceae) by silica gel column chromatog raphy. Based on spectral (IR,1H NMR and MS)analysis and chemical reactions their structures were idenntified as(Ⅰ)and (Ⅱ) respectively. |
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| Keywords: | Thymelaceae Volatile oil Sesquiterpenoids Baimuxinol Dehydrobaimuxinol Aquilaria sinensis (Lour ) Gilg |
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