| RAFT聚合制备氟硅嵌段共聚物及结构性能 |
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| 引用本文： | 赵镇,李慧,郭燕莉,王友付,韩哲文.RAFT聚合制备氟硅嵌段共聚物及结构性能[J].医学教育探索,2011,24(2). |
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| 作者姓名： | 赵镇 李慧 郭燕莉 王友付 韩哲文 |
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| 作者单位： | 华东理工大学材料科学与工程学院， 上海 200237;华东理工大学材料科学与工程学院， 上海 200238;华东理工大学材料科学与工程学院， 上海 200239;华东理工大学材料科学与工程学院， 上海 200240;华东理工大学材料科学与工程学院， 上海 200241 |
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| 基金项目： | 上海市自然科学基金(10ZR1407600) |
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| 摘 要： | 以三硫代酯封端的聚二甲基硅氧烷作为大分子链转移剂，通过可逆加成断裂链转移聚合(RAFT)制备了一系列聚二甲基硅氧烷-b-聚甲基丙烯酸十二氟庚酯 (PDMS-b-PDFHMA)二嵌段共聚物。利用凝胶渗透色谱(GPC)、傅里叶变换红外光谱(FTIR)、氢核磁共振谱(1H-NMR)对该嵌段共聚物的组成、结构和分子量进行了表征，并通过接触角测量对其表面性能进行了研究。结果表明，该嵌段共聚物具有预期结构，分子量可控，表面性能优异。
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| 关 键 词： | RAFT聚合 氟硅嵌段共聚物 表面性能 反应动力学 |
Synthesis and Characterization of Fluoro Silicone Block Copolymers Prepared via RAFT Polymerization |
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| ZHAO Zhen,LI Hui,GUO Yan-li,WANG You-fu and HAN Zhe-wen.Synthesis and Characterization of Fluoro Silicone Block Copolymers Prepared via RAFT Polymerization[J].Researches in Medical Education,2011,24(2). |
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| Authors: | ZHAO Zhen LI Hui GUO Yan-li WANG You-fu and HAN Zhe-wen |
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| Institution: | School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200238, China;School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200239, China;School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200240, China;School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200241, China |
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| Abstract: | A series of well defined polydimethylsiloxane-b-polydodecafluoroheptylmethacrylate diblock copolymers (PDMS-b-PDFHMA) were prepared via RAFT polymerization using trithiocarbonate termi nated polydimethylsiloxane as a macromolecular chain tranfer agent. The molecular weights and chemical structures of the fluoro silicone diblock copolymers were characterized by GPC, 1H-NMR and FT-IR. The effect of fluorine content on surface energy was also investigated by static contact angle measurement. Results show that dibockcopolymers have the controllable molecular weights and excellent surface properties. |
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| Keywords: | RAFT polymerization fluoro silicone diblock copolymer surface properties kinetics |
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