| 湖北贝母化学成分的研究 Ⅲ.湖贝甲素甙的分离和鉴定 |
| |
| 引用本文： | 吴继洲,濮全龙. 湖北贝母化学成分的研究 Ⅲ.湖贝甲素甙的分离和鉴定[J]. 药学学报, 1985, 20(5): 372-376 |
| |
| 作者姓名： | 吴继洲 濮全龙 |
| |
| 作者单位： | 湖北省药品检验所,武汉;**广西中医药研究所 |
| |
| 摘 要： | 本文报道了自湖北贝母Fritillaria hupehensis Hsiao et K.C.Hsia醇提取总生物碱中分离到一种新的生物碱甙,C83H55NO7,mp 241～244℃。经红外光谱、核磁共振氢谱及质谱分析,结合水解及衍生物的制备证明生物碱甙的结构为5α,14α-瑟瓦林-6α-羟基-3αβ-D-葡萄糖甙,命名为湖贝甲素甙(hupeheninoside)。
|
| 关 键 词： | 湖北贝母 浙贝甲素 浙贝乙素 湖贝甲素 湖贝甲素甙 C-去甲-D-高甾体生物碱 |
| 收稿时间： | 1984-05-17 |
Studies on the chemical constituents of hubeibeimu (Fritillaria hupehensis Hsiao et K. C. Hsia). III. Isolation and identification of hupehenioside |
| |
| WU Ji-Zhou and PU Quan-Long. Studies on the chemical constituents of hubeibeimu (Fritillaria hupehensis Hsiao et K. C. Hsia). III. Isolation and identification of hupehenioside[J]. Acta pharmaceutica Sinica, 1985, 20(5): 372-376 |
| |
| Authors: | WU Ji-Zhou and PU Quan-Long |
| |
| Abstract: | An new C-nor D-homosteroid glucoside, C33H55NO7, mp 241～244℃, 241～244℃, named hupeheninoside, was isolated from the bulb of Fritillaria hupehensis Hsiao et K. C. Hsia by column chromatographic techniques.On the basis of the 1H-NMR, FD-and EI-mass spectra of hupeheninoside and the products of its transfomation, the structure and configuration of hupeheninoside have been established as 5α, 14α-cevanine-6α-hydroxyl-3α-β-D-glucoside (Ⅳ). |
| |
| Keywords: | Peimine Peiminine Hupehenine Hupeheninoside Cnor-D-homosteroid alkaloid Hubei beimu |
|
| 点击此处可从《药学学报》浏览原始摘要信息 |
|
点击此处可从《药学学报》下载全文 |
|
