Potentiometric investigation of the stability of palladium(II) complex of pralidoxime chloride in aqueous solution |
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| Authors: | K Karljikovi&#x;-Raji&#x; B Stankovi&#x; |
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| Institution: | Faculty of Pharmacy, Institute of Analytical Chemistry, Belgrade, Yugoslavia |
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| Abstract: | The formation of a complex between palladium(II) chloride and pralidoxime chloride (PAM-2Cl) has been studied by means of potentiometric pH measurements. The real stability constant of the complex in aqueous medium of ionic strength 0.3 M (KCl) at 25.0°C was log Ks = 7.29. This value was close to that (log Ks = 7.02) obtained previously by spectrophotometric methods after appropriate correction with respect to the corresponding value of the acidic constant of PAM-2Cl (pKca = 8.05), which was also determined under the same experimental conditions. |
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| Keywords: | Pralidoxime chloride palladium(II) complex acidic constant stability constant potentiometric determination |
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