NiFe2O4@ nitrogen-doped carbon hollow spheres with highly efficient and recyclable adsorption of tetracycline

Antibiotics can affect ecosystems and threaten human health; therefore, methods for removing antibiotics have become a popular subject in environmental management and for the protection of human health. Adsorption is considered an effective approach for the removal of antibiotics from water. In this study, NiFe₂O₄@nitrogen-doped carbon hollow spheres (NiFe₂O₄/NCHS) were synthesized via a facile hydrothermal method followed by calcination using NCHS as a hard template. The nanocomposite exhibited high adsorption activity and good recyclability. The nanocomposite was characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and nitrogen adsorption–desorption to study its micromorphology, structure, and chemical composition/states. In addition, the factors affecting the adsorption process were systematically investigated, including tetracycline (TC) concentration, solution pH, ionic strength, and temperature. The maximum adsorption capacity for TC was calculated to be 271.739 mg g⁻¹ based on the Langmuir adsorption model, which was higher than various other materials. This study provides an effective method for constructing the NiFe₂O₄/NHCS core–shell structure, which can be applied for the removal of TC from water.

Antibiotics can affect ecosystems and threaten human health; therefore, methods for removing antibiotics have become a popular subject in environmental management and for the protection of human health.