Green synthesis of palladium nanoparticles using lentinan for catalytic activity and biological applications |
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Authors: | Zengsheng Han Le Dong Jin Zhang Tianming Cui Shengfu Chen Guanglong Ma Xiaolei Guo Longgang Wang |
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Institution: | Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 China.; College of Chemistry and Environmental Engineering, Shanxi Datong University, Datong 037009 China ; Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027 China |
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Abstract: | The green synthesis of palladium nanoparticles (Pd NPs) for catalysis and biological applications has been gaining great interest. To replace complex plant extracts, lentinan (LNT) may be a good reducing and stabilizing agent. In this work, a simple and green method using LNT to reduce and stabilize palladium Pd NPs was verified. The resulting LNT stabilized palladium nanoparticles (Pdn-LNT NPs) were characterized by UV-Vis spectroscopy, DLS, TEM, and XPS. The results indicated that Pd NPs inside of Pdn-LNT NPs had a small size (2.35–3.32 nm). Pdn-LNT NPs were stable in solution for 7 days. In addition, Pdn-LNT NPs had higher catalytic activity towards the reduction of 4-nitrophenol than other catalysts. More importantly, Pdn-LNT NPs had negligible cytotoxicity towards cells and showed good antioxidant activity. Taken together, the prepared Pdn-LNT NPs have great potential bio-related applications.Lentinan stabilized palladium nanoparticles had high catalytic activity, negligible cytotoxicity and good antioxidant activity. |
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