Syntheses,structures, and magnetic properties of mixed-ligand complexes based on 3,6-bis(benzimidazol-1-yl)pyridazine |
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| Authors: | Jun-Liang Dong Peng-Yin Zhu Jia-Qiang Du Fei Xie Hai-Ming Lan Ru-Xia Yang Li-Zheng Yang Duo-Zhi Wang |
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| Institution: | School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 P. R. China.; Key Laboratory of Energy Materials Chemistry, Ministry of Education, Urumqi 830046 Xinjiang P. R. China |
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| Abstract: | Six new metal–organic coordination polymers (CPs) Ni(L)(2,5-TDC)(H2O)]n(1), Ni(L)(1,3-BDC)(H2O)]n (2), Ni(L)(1,4-BDC)(H2O)]n (3), Mn(L)(2,5-TDC)(H2O)]n (4), Mn(L)(2,6-PYDC)(H2O)]n (5) and Mn(L)(1,4-NDC)]n (6) were achieved by reactions of the corresponding metal salt with mixed organic ligands (L = 3,6-bis(benzimidazol-1-yl)pyridazine, 2,5-H2TDC = thiophene-2,5-dicarboxylic acid, 1,3-H2BDC = isophthalic acid, 1,4-H2BDC = terephthalic acid, 2,6-H2PYDC = pyridine-2,6-dicarboxylic acid, 1,4-H2NDC = naphthalene-1,4-dicarboxylic acid) under solvothermal condition. CPs 1–6 were characterized by single-crystal X-ray diffraction, IR, TG, XRD and elemental analyses. Their structures range from the intricate 3D CPs 1, 3, 4 and 6 to the 2D coordination polymer 2 and the infinite 1D chain 5. The CPs 1–4 and 6 underlying networks were classified from the topological viewpoint, disclosing the distinct sql (in 1), pcu (in 3 and 6), new topology (in 2), and dia (in 4) topological nets. Moreover, analysis of thermal stability shows that they had good thermal stability. Finally, magnetic properties of CPs 1–6 have been studied, the results showed that complex 2 had ferromagnetic coupling and complexes 1, 3–6 were antiferromagnetic.Six new metal–organic coordination polymers were prepared by reactions of the corresponding metal salt with mixed organic ligands under solvothermal conditions. The compounds were structurally, magnetically and catalytically characterized. |
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