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Formation of highly ordered micro fillers in polymeric matrix by electro-field-assisted aligning
Authors:Yajun Zhang  Xiangwen Zheng  Weitao Jiang  Jie Han  Jiangtao Pu  Lanlan Wang  Biao Lei  Bangdao Chen  Yongsheng Shi  Lei Yin  Hongzhong Liu  Feng Luo  Xiaokang Liu  Jinju Chen
Affiliation:State Key Laboratory for Manufacturing Systems Engineering, Xi''an Jiaotong University, Xi''an 710054 China.; Shaanxi Joint Laboratory for Graphene, China ; IMDEA Nanoscience, Faraday 9, Ciudad Universitaria de Cantoblanco 28049, Madrid Spain ; Engineering Research Center of Mechanical Testing Technology and Equipment, Chongqing University of Technology, Chongqing 400050 China ; School of Engineering, Newcastle University, UK
Abstract:Nanocomposites composed by polymeric matrix with micro/nano fillers have drawn lots of attention since their dramatic properties beyond pristine polymers. The spatial distribution of the micro/nano fillers in the polymeric matrix determines the final desired properties of the nanocomposites, thus deserves to investigate. Here, we proposed an effective method of assembling the micro/nano fillers to pre-designed patterns within the polymeric matrix by AC-electro-field-assisted aligning. By pre-designed AC electric fields which could be dynamically controllable, the distribution of microparticles (acting as fillers) in the matrix was tuned to various patterns related to the electric fields, such as linear alignment and circular alignment. The field-oriented particles chains could act as endoskeletal structures, showing unique properties (i.e., mechanical, optical, and anisotropic properties) beyond those of the conventional composites with randomly distributed particles.

Nanocomposites composed by polymeric matrix with micro/nano fillers have drawn lots of attention since their dramatic properties beyond pristine polymers.
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