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2D nanoporous Ni(OH)2 film as an electrode material for high-performance energy storage devices
Authors:Jinjun Tian  Yan Xue  Xinping Yu  Yuanchao Pei  Hucheng Zhang  Jianji Wang
Affiliation:Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang Henan 453007 China.; School of Biological and Chemical Engineering, Nanyang Institute of Technology, Nanyang Henan 473004 China
Abstract:A two-dimensional (2D) nanoporous Ni(OH)2 film was successfully developed from triethanolamine (TEA) as the alkali source and soft template using a scalable hydrothermal technique. The nanostructured Ni(OH)2 film was flexible and translucent, and could be directly compressed on a current collector. Owing to the uniform well-defined morphology and stable structure, the Ni(OH)2 film binder-free electrode displayed a high specific capacity, exceptional rate capability, and admirable cycle life. The specific capacitance was 453.6 mA h g−1 (1633 F g−1) at 0.5 A g−1. The assembled Ni(OH)2//activated carbon (AC) asymmetric supercapacitor (ASC) device had an energy density of 58.7 W h kg−1 at a power density of 400 W kg−1. These prominent electrochemical properties of Ni(OH)2 were attributed to the high electrical conductivity, high surface area, and unique porous architecture. Free tailoring, binder-free, and direct pressing were the most significant achievements of the Ni(OH)2 film in the development of high-performance energy storage devices.

A two-dimensional (2D) nanoporous Ni(OH)2 film was successfully developed from triethanolamine (TEA) as the alkali source and soft template using a scalable hydrothermal technique.
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