| 川楝子中的化学成分研究 |
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| 引用本文： | 陈琳,穆淑珍,晏晨,黄烈军,郝小江. 川楝子中的化学成分研究[J]. 中国实验方剂学杂志, 2013, 19(18): 90-95 |
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| 作者姓名： | 陈琳 穆淑珍 晏晨 黄烈军 郝小江 |
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| 作者单位： | 1. 贵州省中国科学院天然产物化学重点实验室,贵阳 550002;贵州大学生命科学学院,贵阳550025
2. 贵州省中国科学院天然产物化学重点实验室,贵阳,550002 |
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| 基金项目： | 国家自然科学基金项目(31160374);国家973计划支撑项目(2012CB722601) |
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| 摘 要： | 目的:研究黔产川楝子中的化学成分.方法:应用正、反相硅胶(RP-18型)柱层析；葡聚糖凝胶(Sephadex LH-20型)柱层析,结合重结晶方法进行分离纯化,运用1 H-NMR,13 C-NMR,ESI-MS和ES-MS等现代波谱技术对化合物的结构进行鉴定.结果:从黔产川楝子乙醇提取物中分离鉴定了12个化合物,分别被鉴定为:1-O-tigloyl-1-O-debenzoylohchinal(1),印楝醛(ohchinal,2),1-cinnamoyhrichilinin (3),3,7-diacetyl-14,15-deoxyhavanensin(4),7-O-acetyl-14,15-deoxyhavanensin(5),6α-O-acetyl-7-deacetylnimocinol (6),6α-hydroxyazadirone (7),24-Nor-5(ょ)-13α,17α-chola-14,20,22-triene-3β,7α-diol-21,23-epoxy-4,4,8-trimethyl-3-acetate(8),hedyotol-A(9),2,6-bis (3-methoxy-4-hydroxyphenyl)-3,7-dioxabicyclo[3,3,0]octan-8-one(10),exo-endo-2,6-bis (4'-hydroxy-3 '-methoxy-phenyl)-3,7-dioxabicyclo[3,3,0]octane (11)和betulafolienediolone (12).结论:化合物2～12均为首次从该植物中分离得到.
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| 关 键 词： | 川楝子 化学成分 分析纯化 结构鉴定 |
| 收稿时间： | 2013-06-05 |
Study on Chemical Constituents of Fructus Melia toosendan |
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| CHEN Lin,MU Shu-zhen,YAN Chen,HUANG Lie-jun and HAO Xiao-jiang. Study on Chemical Constituents of Fructus Melia toosendan[J]. China Journal of Experimental Traditional Medical Formulae, 2013, 19(18): 90-95 |
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| Authors: | CHEN Lin MU Shu-zhen YAN Chen HUANG Lie-jun HAO Xiao-jiang |
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| Affiliation: | Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550022, China;School of Life Science, Guizhou University, Guiyang 550025, China;Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550022, China;Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550022, China;Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550022, China;Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550022, China |
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| Abstract: | |
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| Keywords: | fructus Melia toosendan chemical constituents separation and purification structural identification |
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