| 评“McCall观察方法”——对一种色谱系统分配效果观察方法的商榷 |
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| 引用本文： | 孙汉涛,安登魁,吴如金.评“McCall观察方法”——对一种色谱系统分配效果观察方法的商榷[J].药学学报,1984,19(2):137-140. |
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| 作者姓名： | 孙汉涛 安登魁 吴如金 |
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| 作者单位： | 南京药学院,*1980届药物分析学研究生 |
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| 摘 要： | 本文通过理论分析和文献数据的分析,对McCall提出的色谱系统分配效果的观察方法提出了不同的看法,认为McCall方法中的所谓logK并不是常数。McCall的方法无论在理论上和实践上都是不妥的。
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| 关 键 词： | McCall观察方法 色谱系统分配效果的观察 容量因子log k′ 分配系数log P |
| 收稿时间： | 1983-02-08 |
McCall's observation method--a discussion on the method of observation of partition efficiency of partition chromatography |
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| SUN Han-tao AN Deng-kui and WU Ru-jin.McCall's observation method--a discussion on the method of observation of partition efficiency of partition chromatography[J].Acta Pharmaceutica Sinica,1984,19(2):137-140. |
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| Authors: | SUN Han-tao AN Deng-kui and WU Ru-jin |
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| Abstract: | The method proposed by McCall in 1975 for the observation of the partition efficiency of partition chromatography has been used recently. A different point of view about the method is raised by theoretical analysis and practical examination. In this paper, we showed that the"log K" in McCall's method is not a constant but varies with log P. So, we consider that McCall's observation method is neither suitable in theory nor in practice. |
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| Keywords: | Observation of partitioning efficiency in chromatographic system Capacity factor log k′ Partition coefficient log P McCall′s observation method |
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