Synthesis of sequentially deuterated 1‐n‐Butyl‐3‐methylimidazolium ionic liquids |
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Authors: | Alexander Khrizman Hiu Yan Cheng Guillermo Moyna |
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Institution: | Department of Chemistry and Biochemistry, University of the Sciences in Philadelphia, 600 South Forty‐Third Street, Philadelphia, PA 19104, USA |
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Abstract: | Deuterium isotopologues of the ionic liquid (IL) 1–n‐butyl‐3‐methylimidazolium chloride (C4mim]Cl) sequentially labeled on the C‐1″, C‐1′, C‐2′, C‐3′, and C‐4′ positions of the N‐alkyl groups were prepared following a strategy that minimizes the number of distinct reactions through the use of analogous synthetic routes. In several cases, good yields after the initial deuterium incorporation reaction were achieved by combining well‐established chemical transformations into efficient single‐step processes. Copyright © 2011 John Wiley & Sons, Ltd. |
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Keywords: | deuteration deuterium isotope effects imidazolium cations ionic liquids |
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