Télomères monofonctionnels du chlorure de vinyle, 4. Synthèse et caractérisation par catalyse rédox

Monofunctional telomers of vinyl chloride ( 1 ) were synthesized by two ways. In the first one, the telomers resulting from the reaction of 1 with carbon tetrachloride were used as telogenic agents to react with allyl acetate leading to a monoadduct. In the second one, monofunctional telogens were used in a redox catalyzed reaction with 1 . Trichloroacetic acid and its esters ( 2b–d ) were applied as telogens. The theoretical maximum yields and the number average degrees of polymerization at these yields were calculated and compared with the experimental results.