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不确定度在测定生活饮用水氯化物分析中的应用
引用本文:白晶,孙晓红,刘彤. 不确定度在测定生活饮用水氯化物分析中的应用[J]. 中国卫生工程学, 2008, 7(6): 361-362
作者姓名:白晶  孙晓红  刘彤
作者单位:哈尔滨市疾病预防控制中心,黑龙江,哈尔滨,150056
摘    要:目的探讨不确定度在测定生活饮用水中氯化物分析中的应用。方法采用GB/T5750.5—2006《生活饮用水标准检验方法无机非金属指标》进行检测,分析不确定度的来源并计算不确定度。结果采用硝酸银容量法测定生活饮用水中氯化物,水样氯化物含量为5.3mg/L时,其合成不确定度:μrel(Cl-)=0.04,μ(Cl-)=C(Cl-)×μrel(Cl-)=0.21mg/L;扩展不确定度:μ=Kμ(Cl-)=0.42mg/L(K=2)。结论置信概率为95%时水样氯化物含量为5.3mg/L,其不确定度为0.42mg/L。

关 键 词:不确定度  氯化物  硝酸银容量法

Uncertainty Application in Determination of Chloride in Drinking Water
BAI Jing,SUN Xiao-hong,LIU Tong. Uncertainty Application in Determination of Chloride in Drinking Water[J]. Chinese Journal of Public Health Engineering, 2008, 7(6): 361-362
Authors:BAI Jing  SUN Xiao-hong  LIU Tong
Affiliation:BAI Jing,SUN Xiao-hong,LIU Tong.Harbin Center for Disease Control and Prevention,Harbin Heilongjiang 150056,China
Abstract:Objective To discuss uncertainty in determination of chloride in drinking water. Methods According to national standards ( GB/T 5750. 5 - 2006 ), chloride in drinking water was detected and sources of uncertainty were analyzed and calculated. Results When the quantity of chloride in water sample was 5.3 mg/L, μrel(Cl-)=0.04,μ(Cl-)=C(Cl-)×μrel(Cl-)=0.21mg/L, and μ=Kμ(Cl-)(K=2)=0.42mg/L Conclusion Uncertainty with the quantity of chloride in water sample is 5.3 mg/L and confidence probability is 95%.
Keywords:Uncertainty  Chloride  Silver nitrate volumetric method  
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