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Effect of Biochar Addition on Mechanical Properties,Thermal Stability,and Water Resistance of Hemp-Polylactic Acid (PLA) Composites
Authors:Mariem Zouari  David B. Devallance  Laetitia Marrot
Affiliation:1.Innorenew CoE, Livade 6, 6310 Izola, Slovenia; (D.B.D.); (L.M.);2.Faculty of Mathematics Natural Sciences and Information Technologies, University of Primorska, Muzejski Trg 2, 6000 Koper, Slovenia;3.Andrej Marušič Institute, University of Primorska, Muzejski Trg 2, 6000 Koper, Slovenia
Abstract:The present study investigated the effect of biochar (BC) addition on mechanical, thermal, and water resistance properties of PLA and hemp-PLA-based composites. BC was combined with variable concentration to PLA (5 wt%, 10 wt%, and 20 wt%) and hemp (30 wt%)-PLA (5 wt% and 10 wt%); then, composites were blended and injection molded. Samples were characterized by color measurements, tensile tests, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and water contact angle analysis. Experimental results showed that adding 5 wt% of BC enhanced the composite’s tensile modulus of elasticity and strength. Hence, the use of optimized loading of BC improved the mechanical strength of the composites. However, after BC addition, thermal stability slightly decreased compared with that of neat PLA due to the catalytic effect of BC particles. Moreover, the water-repelling ability decreased as BC content increased due to the specific hydrophilic characteristics of the BC used and its great porosity.
Keywords:biochar   polylactic acid   hemp fibers   mechanical properties   thermal stability   water resistance
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