Anionic polymerization of carbazolyl-substituted oxiranes initiated by potassium alkalide,potassium tert-butoxide and potassium hydride |
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| Authors: | Gintaras Buika,Juozas V. Gra ulevi
ius,Andrzej Stolarzewicz,Zbigniew Grobelny |
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| Affiliation: | Gintaras Buika,Juozas V. Gražulevičius,Andrzej Stolarzewicz,Zbigniew Grobelny |
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| Abstract: | The influence of the kind of initiating system and the addition of a crown ether on the anionic polymerization of oxiranes with a carbazoyl substituent is described. Potassium alkalide, potassium tert-butoxide and potassium hydride were used as initiators. Selecting a suitable initiator and crown ether concentration, carbazolyl-containing polymers with polymerization degrees from 4 to 60 can be produced. Using a suspension of potassium hydride in tetrahydrofuran, polymers with relatively high molar masses were obtained. |
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