Palladium nanoparticles as efficient catalyst for C–S bond formation reactions |
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| Authors: | Mei-Na Zhang Shahid Khan Junjie Zhang Ajmal Khan |
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| Affiliation: | Department of Applied Chemistry, School of Science, Xi''an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi''an Jiao Tong University, Xi''an 710049 P. R. China, |
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| Abstract: | The development of green, economical and sustainable chemical processes is one of the primary challenges in organic synthesis. Herein, we report an efficient and heterogeneous palladium-catalyzed sulfonylation of vinyl cyclic carbonates with sodium sulfinates via decarboxylative cross-coupling. Both aliphatic and aromatic sulfinate salts react with various vinyl cyclic carbonates to deliver the desired allylic sulfones featuring tri- and even tetrasubstituted olefin scaffolds in high yields with excellent selectivity. The process needs only 2 mol% of Pd2(dba)3 and the in situ formed palladium nano-particles are found to be the active catalyst.Heterogenous catalysis: economical and sustainable synthesis of allylic sulfone featuring tri- and even tetrasubstituted olefin scaffold via decarboxylative cross-coupling from vinyl cyclic carbonates with sodium sulfinates using PdNPs as a catalyst. |
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