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山芝麻中三个新三萜化合物的结构测定
引用本文:刘卫国,王明时. 山芝麻中三个新三萜化合物的结构测定[J]. 药学学报, 1985, 20(11): 842-851
作者姓名:刘卫国  王明时
作者单位:南京药学院;*1985年研究生
摘    要:从梧桐科植物山芝麻(Helicteres angustifolia L.)的根中分离出6种成分。其中3种为已知化合物β-谷甾醇(β-sitosterol),白桦脂酸(betulic acid)和齐墩果酸(oleanolic acid)。其余3种为新的三萜类化合物,命名为山芝麻酸甲酯(methyl helicterate),山芝麻宁酸甲酯(methyl helicterate)和山芝麻宁酸(helicterilic acid)。其化学结构经光谱分析和衍生物制备分别推定为Ⅰ,Ⅱ和Ⅳ。

关 键 词:山芝麻  山芝麻酸甲酯  山芝麻宁酸甲酯  山芝麻宁酸
收稿时间:1984-11-07

STRUCTURE DETERMINATION OF THREE NEW TRIERP HELICTERES ANGUSTIFOLIA LINN ENOIDS
LIU Wei-Guo and WANG Ming-Shi. STRUCTURE DETERMINATION OF THREE NEW TRIERP HELICTERES ANGUSTIFOLIA LINN ENOIDS[J]. Acta pharmaceutica Sinica, 1985, 20(11): 842-851
Authors:LIU Wei-Guo and WANG Ming-Shi
Abstract:Six chemical constituents (Ⅰ-Ⅵ) were isolated from the roots of Helieteres angustifolia L.. Three of them were shown to be identical with β-sitosterol, betulic acid and oleanolic acid. The other three were found to be new triterpenoids, named methyl helicterate, methyl helicterilate and helicterilic acid with structures elucidated as Ⅰ, Ⅱ and Ⅳ respectively, on the basis of spectroscopic analysis and preparation of derivatives.
Keywords:Methyl helicterate  Methyl helicterilate  Helicterilic acid  Helicteres angustifolia L.
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