Zur Aminolyse von trans-3-Phenylglycidsäure-Derivaten, 5. Mitt. Unterscheidung N-substituierter 3-Phenylserin- und 3-Phenylisoserin-Derivate |
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Authors: | J. Wilhelm Tack Jochen Lehmann Felix Zymalkowski |
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Abstract: | Aminolysis of Derivatives of trans-3-Phenylglycidic Acid, V: Distinction Between N-Substituted Derivatives of 3-Phenylserine and 3-Phenylisoserine Derivatives of trans-3-phenylglycidic acid react with primary and secondary aliphatic amines to give derivatives of erythro-3-phenylisoserine. Hydrogenolysis of the N-benzyl or O-benzyl moiety allows better than other methods to distinguish between derivatives of 3-phenylserine and 3-phenylisoserine. The structural proof reported in5) is not correct. |
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