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A new method for rapid determination of the potential of zero charge for gold
Authors:JinHua Chen  LiHua Nie  ShouZhuo Yao
Affiliation:Department of Chemistry and Chemical Engineering, Hunan University, ChangSha 410082, People''s Republic of China
Abstract:A new method, based on the response of a thickness shear mode sensor to electrocapillary phenomena, for determination of the potential of zero charge (pzc) at solid metal (solution interfaces is described. The pzc values of gold in the solutions of NaF, Na2SO4, and HClO4 are obtained. The order of the pzc values is as follows: F?> ClO4?> SO42?. This is in good agreement with previous work.
Keywords:Potential of zero charge  Thickness shear mode sensor  Gold  Electrocapillary  Interfacial tension
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