| Mn（OAc）_2·4H_2O和有机酸固相反应的研究 |
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| 引用本文： | 傅岩.Mn（OAc）_2·4H_2O和有机酸固相反应的研究[J].东南大学学报(医学版),1995(3). |
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| 作者姓名： | 傅岩 |
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| 作者单位： | 南京铁道医学院化学教研室 |
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| 摘 要： | 用等温电导法研究了Ｍｎ（ＯＡｃ）２·４Ｈ２Ｏ与有机酸的固相反应。发现反应活性为：戊二酸（Ｅａ＝３７．６１ｋＪ·ｍｏｌ－１）＞丁二酸（Ｅａ＝４１．３４ＫＪ·ｍｏｌ－１）＞己二酸（Ｅａ＝８５．２０ｋＪ·ｍｏｌ－１）。用元素分析、ＸＲＤ和ＩＲ表征了固相产物。
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| 关 键 词： | 固相反应 等温电导法 醋酸锰 有机酸 |
^ STUDIES ON SOLID STATE REACTIONS OF MANGANESE ACETATE TETRAHYDRATE WITH
ORGANIC ACIDS |
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| Fu Yan.^ STUDIES ON SOLID STATE REACTIONS OF MANGANESE ACETATE TETRAHYDRATE WITH
ORGANIC ACIDS[J].Journal of Southeast Univ: Medical Sci Ed,1995(3). |
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| Authors: | Fu Yan |
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| Abstract: | he solid state reactions of manganese acetate tetrahydrate
with organic acids were studiedby isothermal electricl conductivity method at room temperature.
The reactivity sequence wasfound as following:glutaric acid(Ea= 37.61 kJ/mol) > succinic
acid(Ea=41. 34 kJ/mol)>adipic acid(Ea= 85. 20 kJ/mol).It is reasoned according to structure why
the reactivity of glutar-ic acid is better than succinic acid.The solid products were characterized
by means of elementalanalysis,XRD and IR spectra. |
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| Keywords: | solid state reaction isothermal electric conductivity manganese acetate te-trahydrate organic acid |
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