Effects of diamine isomers on the properties of colorless and transparent copoly(amide imide)s |
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Authors: | Moon Young Choi Seon Ju Lee Lee Ku Kwac Hong Gun Kim Jin-Hae Chang |
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Institution: | Graduate School of Carbon Convergence Engineering, Jeonju University, Jeonju 55069 Korea ; Institute of Carbon Technology, Jeonju University, Jeonju 55069 Korea, |
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Abstract: | To fully understand the structure–property relationship of aromatic copoly(amide-imide)s (Co-PAIs) and determine which factors lead to chain rigidity, we prepared two series of Co-PAIs. They were synthesized from two types of amine monomers containing m- and p-isomers and different ratios of 4,4′-(hexafluoroiso-propylidene)diphthalic anhydride (6FDA) and 4,4′-biphthalic anhydride (BPA). m-Substituted and p-substituted N,N′-2,2′-bis(trifluoromethyl)-4,4′-biphenylene]bis(aminobenzamide) (MPAB) diamine isomers were synthesized from 3- and 4-nitrobenzoyl chloride and 2,2′-bis(trifluoromethyl) benzidine (TFB), respectively. The Co-PAI films were synthesized from poly(amic acid) (PAA), via solution-casting, followed by thermal imidizations. The thermal- and mechanical-properties and optical transparency of the Co-PAI films with different BPA monomer contents were investigated. We also investigated the effects of the different MPAB isomers on the Co-PAI structures. Compared with the m-substituted MPAB Co-PAI films, the p-substituted MPAB Co-PAI films have superior thermo-mechanical properties at the same monomer content. However, the optical transparencies of the m-MPAB Co-PAIs are slightly better than those of the p-MPAB Co-PAIs.The thermal- and mechanical-properties and optical transparency of the copoly(amide imide) films with different BPA monomer contents were investigated. |
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