Preparation of self-healing polyurethane/functionalized graphene nanocomposites as electro-conductive one part adhesives |
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Authors: | Farzaneh Hashemi Nasr Mehdi Barikani Mehdi Salehirad |
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Institution: | Chemistry and Process Department, Niroo Research Institute, P.O. Box 1468613113 Tehran Iran ; Department of Polyurethane and Advanced Materials, Iran Polymer and Petrochemical Institute, P.O. Box 14965/115 Tehran Iran, |
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Abstract: | We report the synthesis and investigation of the electrical conductivity and self-healing properties of moisture curable polyurethane (PU) adhesives filled with functionalized graphene nanosheets and isophorone diisocyanate (IPDI) loaded poly(methyl methacrylate) (PMMA) nanocapsules. For this purpose, chemically functionalized graphene was prepared by covalently grafting 4-(4,5-diphenyl-1H-imidazol-2-yl)phenol (DIP) on the surface of graphene oxide and synthesized PMMA nanocapsules were loaded with IPDI. Both nanofillers were then dispersed in a polyurethane matrix and the effects on the adhesion properties of the adhesives in aluminum–aluminum metal joints were studied. The results showed that by surface modification and better exfoliation of graphene nanosheets, the electrical conductivity was increased from 2.2 × 10−9 S m−1 to 4.1 S m−1 for pure PU and 10 wt% graphene based nanofiller loaded PU, respectively. The thermal stability, electrical conductivity, shear strength and self-healing process of the ECAs were also studied. The results provide evidence that the prepared adhesives have the potential for applications in electronic device packaging.One part moisture curable adhesives based on polyurethane/functionalized graphene nanocomposites were synthesized and showed good electrical conductivity, thermal stability, shear strength and self-healing properties. |
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