Photoreduction properties of novel Z-scheme structured Sr0.8La0.2(Ti1−δ4+Tiδ3+)O3/Bi2MoO6 composites for the removal of Cr(vi) |
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Authors: | Bin Liu Zhili Fan Wangjian Zhai Junfeng He Shaofeng Wang Fuming Chen Yinzhen Wang Wei Li Xianhua Hou Qinyu He |
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Affiliation: | Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, Guangdong Provincial Engineering Technology Research Center for Quantum Precision Measurement, Guangdong Provincial Engineering Technology Research Center of Efficient Green Energy and Environmental Protection Materials, School of Physics and Telecommunication Engineering, South China Normal University, China, |
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Abstract: | Novel Z-scheme structured Sr0.8La0.2(Ti1−δ4+Tiδ3+)O3/Bi2MoO6 (LSTBM) composites were prepared via a facile two-step solvothermal method. Several characterization techniques were employed to investigate the phases, microstructures, compositions, valence states, oxygen vacancies, surface oxygen absorption, energy band structures and lifetime of photoproduced carriers. It was found that the lifetime and transfer of the photoproduced carriers of LSTBM were better than those of Bi2MoO6 (BMO) and Sr0.8La0.2(Ti1−δ4+Tiδ3+)O3 (LSTO). The LSTBM with a molar ratio of BMO/(LSTO + BMO) = 0.07 (denoted as LSTBM7) showed 1.9 and 3.1 times removal rates than those for BMO and LSTO, respectively. Importantly, the built-in electric field in the heterojunction of LSTBM and Ov-s, especially in Ov-s on the higher-Fermi-level side of the heterojunction, had co-played roles in prolonging the lifetime and improving the transfer of photogenerated carriers. The photoproduced e− played a dominant role in reducing Cr(vi) to Cr(iii) and the produced Cr(iii) tends to form Cr(OH)3 and adsorb onto the surface of the photocatalyst to decrease the nucleation energy. The possible reduction route for Cr(vi) to Cr(iii) over LSTBM7 was figured out. This study implies that inducing Ov-s on the higher-Fermi-level side of the Z-scheme heterojunction is a more effective route for separating the photogenerated electrons and holes and improving the transfer of photogenerated carriers.Found an effective way to improve the lifetime and transfer of photogenerated carriers: extrinsic Ov-s in the higher-Fermi-level side of the heterojunction. Z-scheme mechanism and Ov-s have synergistic effect on improving photocatalytic performance. |
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