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山莓中两个新二萜的分离与鉴定
引用本文:张敏,曹庸,杜方麓,欧阳文,袁勇.山莓中两个新二萜的分离与鉴定[J].药学学报,2007,42(11):1155-1158.
作者姓名:张敏  曹庸  杜方麓  欧阳文  袁勇
作者单位:1. 湖南农业大学,生物科学技术学院,湖南,长沙,410128;吉首大学,林产化工工程重点实验室,湖南,张家界,427000
2. 湖南农业大学,生物科学技术学院,湖南,长沙,410128;华南农业大学,食品科学学院,广东,广州,510642
3. 湖南中医药大学,药学院,湖南,长沙,410007
4. 吉首大学,林产化工工程重点实验室,湖南,张家界,427000
基金项目:湖南省教育厅重点科技计划项目;湖南省科技厅重点科技计划项目
摘    要:为研究山莓(Rubus corchorifolius L.f)的化学成分,应用硅胶柱色谱进行分离纯化,根据化合物的理化性质和波谱数据鉴定结构。本文分离鉴定了2个贝壳杉烷二萜化合物,其结构分别为对映-贝壳杉烷-3α,16α,17,19-四醇(1),对映-2-羰基-16α-羟基-贝壳杉烷-17-β-D-葡糖苷(2)。化合物1、2均为新化合物。

关 键 词:山莓  贝壳杉烷二萜  分离与鉴定
文章编号:0513-4870(2007)11-1155-04
收稿时间:2007-05-27
修稿时间:2007-05-27

Isolation and identification of two new diterpenoid from Rubus corchorifolius L.f
ZHANG Min,CAO Yong,DU Fang-lu,OU-YANG Wen,YUAN Yong.Isolation and identification of two new diterpenoid from Rubus corchorifolius L.f[J].Acta Pharmaceutica Sinica,2007,42(11):1155-1158.
Authors:ZHANG Min  CAO Yong  DU Fang-lu  OU-YANG Wen  YUAN Yong
Institution:1. College of Biological Science and Technology, Hunan Agriculture University, Changsha 410128, China ; 2. Key Laboratory of Forest Products and Chemical Engineering, Jishou University, Zhangjiajie 427000, China ; 3. College of Food Science, South-China Agriculture University, Guangzhou 510642, China; 4. Pharmacy College, Hunan University of Traditional Chinese Medicine, Changsha 410007, China
Abstract:To study the constituents of Rubus corchorifolius L. f, the constituents were separated by using various chromatographies and the structures were identified on the basis of chemical and spectral analysis. Two compounds were isolated from Rubus corchorifolius L. f. Their structures were identified as ent-kauran-3beta, 16beta, 17, 19-tetrol (1), ent-2-carbonyl-16beta-hydroxy-kauran-17-beta-D-glucoside (2). Compounds 1 and 2 are new compounds.
Keywords:Rubus corchorifolius L  f  kauran diterpene  isolation and identification
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