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藤香树中二个新的脂肪硝基酚苷的鉴定藤香树中二个新的脂肪硝基酚苷的鉴定
引用本文:吴彤,孔德云,李惠庭.藤香树中二个新的脂肪硝基酚苷的鉴定藤香树中二个新的脂肪硝基酚苷的鉴定[J].药学学报,2004,39(7):534-537.
作者姓名:吴彤  孔德云  李惠庭
作者单位:上海医药工业研究院,上海,200040
摘    要:目的研究藤香树Schisandra propinqua (Wall.) Baill var. intermidia A.C.Smith茎藤的化学成分。方法 应用多种色谱技术进行分离纯化,根据化合物的理化性质和光谱数据分析鉴定结构。结果分离得到7个化合物,分别鉴定为6′-O-α-L-arabinofuranosylthalictoside (1), 6′-O-β-D-apiofuranosylthalictoside (2), thalictoside (3), icariside D2(4), prinsepiol (5), (+)-1-hydroxypinoresinol (6)和(+)-medioresinol (7)。结论化合物1和2为新的脂肪硝基酚苷化合物,其余均为首次从藤香树中获得。

关 键 词:藤香树  脂肪硝基酚苷  6′-O-α-L-arabinofuranosylthalictoside  6′-O-β-D-apiofuranosylthalictoside
收稿时间:2003-09-10

Identification of the structure of two new nitro group phenolic glycosides from Schisandra propinqua (Wall.) Baill var. intermidia A.C.Smith
WU Tong,KONG De-yun,LI Hui-ting.Identification of the structure of two new nitro group phenolic glycosides from Schisandra propinqua (Wall.) Baill var. intermidia A.C.Smith[J].Acta Pharmaceutica Sinica,2004,39(7):534-537.
Authors:WU Tong  KONG De-yun  LI Hui-ting
Institution:Shanghai Institute of Pharmaceutical Industry, Shanghai 200040, China. Tongwu8@hotmail.com
Abstract:AIM: To study the bioactive components from Schisandra propinqua (Wall.) Baill var. intermidia A. C. Smith. METHODS: Compounds were separated with a combination of multichromatography. Their chemical structures were determined on the basis of spectral analysis and chemical evidence. RESULTS: Seven compounds were isolated from the leaves of Helicia nilagirica. The structures were elucidated as 6'-O-alpha-L-arabinofuranosylthalictoside (1), 6'-O-beta-D-apiofuranosylthalictoside (2), thalictoside (3), icariside D2 (4), prinsepiol (5), (+)-1-hydroxypinoresinol (6) and (+)-medioresinol (7). CONCLUSION: Two compounds are new nitro phenolic glycosides.
Keywords:nitro phenolic glycosides  lignans  6′-O-α-L-arabinofuranosylthalictoside  6′-O-β-D-apiofuranosylthalictoside  Schisandra propinqua
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