| 2(RS)-D-葡萄糖-(1′,2′,3′,4′,5′-五羟基戊烷)噻唑烷-4(R)-羧酸与某些二价金属生成的配合物 |
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| 引用本文： | 张英侠,胡凌云,郜文,朱莹.2(RS)-D-葡萄糖-(1′,2′,3′,4′,5′-五羟基戊烷)噻唑烷-4(R)-羧酸与某些二价金属生成的配合物[J].首都医学院学报,1993(3). |
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| 作者姓名： | 张英侠 胡凌云 郜文 朱莹 |
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| 作者单位： | 首都医学院化学教研室，首都医学院化学教研室，首都医学院化学教研室，首都医学院化学教研室 |
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| 摘 要： | 合成了葡萄糖和半胱氨酸的缩合产物,即2(RS)-D-葡萄糖-(1′,2′,3′,4′,5′-五羟基戊烷)噻唑烷-4(R)-羧酸,并分别制备了与锌(Ⅱ)、铜(Ⅱ)、锰(Ⅱ)、钴(Ⅱ)和镍(Ⅱ)等人体必需微量元素形成的配合物。通过元素分析、摩尔电导、热重分析、红外及电子光谱等数据,探讨了上述配合物的的化学结构。
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| 关 键 词： | D-葡萄糖 金属螯合物 微量元素 |
The Complexes of 2(RS)-D-Gluco-(1′,2′,3′,4′,5′-Pentahydroxypentyl)Thiazolidine-4(R)-Carboxylic Acid with Some Metal(Ⅱ)Ions |
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| Zhang Yingxia Hu Lingyun Gao Wen Zhu Ying.The Complexes of 2(RS)-D-Gluco-(1′,2′,3′,4′,5′-Pentahydroxypentyl)Thiazolidine-4(R)-Carboxylic Acid with Some Metal(Ⅱ)Ions[J].Journal of Capital University of Medical Sciences,1993(3). |
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| Authors: | Zhang Yingxia Hu Lingyun Gao Wen Zhu Ying |
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| Institution: | Zhang Yingxia Hu Lingyun Gao Wen Zhu Ying Department of Chemistry,Capital Institute of Medicine |
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| Abstract: | 2(RS)-D-Gluco-(1',2',3',4',5'-Pentahydroxypentyl)Thiazolidine-4(R)-Carboxylic Acid has been synthesized by condensation between D-glucose and L-cysteine.Using this compound as ligand we prepared five novel metal complexes.They are complexes of Zn(Ⅱ), Fe(Ⅱ),Mn(Ⅱ),Cu(Ⅱ),Ni(Ⅱ),respectively.Their composition and structure were char- acterized and studied by molar conductivity,element analysis,thermogravimetry,infrared and UV-spectra. |
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| Keywords: | D-glucose chelate of metal ion trace-element |
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