| 中坝鹅掌叶附子中的生物碱研究Ⅰ |
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| 引用本文： | 王宪楷 赵同芳. 中坝鹅掌叶附子中的生物碱研究Ⅰ[J]. 中国药学杂志, 1995, 30(12): 716-719 |
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| 作者姓名： | 王宪楷 赵同芳 |
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| 作者单位： | 华西医科大学药学院天然药物化学教研室 |
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| 摘 要： | 从中坝（今名江油）３种栽培附于（ＡｃｏｎｉｔｕｍｃａｒｍｉｃｈａｅｌｉＤｅｂｘ．）之一的鹅掌叶附子中，分得１０种生物碱化合物，经几种光谱分析鉴定，证明其中２种为已知生物碱次乌头碱（ｈｙｐａｃｏｎｉｔｉｎｅ）和新乌头碱（ｍｅｓａｃｏｎｉｔｉｎｅ），还获得一种为新化合物，Ｎ－ＣＨＯＣ＿（１９）－二枯生物碱，命名为ａｌｄｏｈｙｐａｃｏｎｉｔｉｎｅ，后者再由ｈｙｐａｃｏｎｉｔｉｎｅ经氧化合成确证。更多还原
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| 关 键 词： | 中坝鹅掌叶附子 aldohypaconitine 次乌头碱 新乌头碱 |
| 收稿时间： | 1995-03-22; |
AlKaloids of cultivated Aconitum carmichaeli Ⅰ |
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| Wang Xiankai,Zhao Tongfang,Lai Sheng. AlKaloids of cultivated Aconitum carmichaeli Ⅰ[J]. Chinese Pharmaceutical Journal, 1995, 30(12): 716-719 |
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| Authors: | Wang Xiankai Zhao Tongfang Lai Sheng |
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| Affiliation: | (School of pharmacy,West China University of Medical Sciences,Chengdu 610041 |
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| Abstract: | A new C19-diterpenoid alkaloid,named aldohypaconitine（1） , was isolated from thelateral roots of O-Zhangye aconite（cultivated Aconitum carmichaeli）from Zhongba. The structureof the new alkaloid has been established by the use of carbon- 13 and proton NMR spectroscopy.Subesquently,this structure was confirmed by chemical correlation with known compound hypa-conitine. This is the first time that aldohypaconitine（1）,an aconitine type N-CHO-diterpenoid al-kaloid,has been found in this plant. Along with this new alkaloid the known alkaloids,hypaconi-tine and mesaconitine were also isolated and characterized. |
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| Keywords: | Aconitum carmichaeli aldohypaconitine hypaconitine mesaconitine |
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