Incréments d'indice de réfraction de polymères en solution: Étude des lois de mélange. Influence de la masse moléculaire et de la structure |
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Authors: | Fran oise Candau,Claude Dufour,Jeanne Fran ois |
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Affiliation: | Françoise Candau,Claude Dufour,Jeanne François |
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Abstract: | The variation of the refractive index increment (dn/dc) with the molecular weight and the structure of series of linear and branched well-defined polystyrenes dissolved in benzene was studied. Testing the Lorenz-Lorentz and Onsager-Böttcher mixture rules, we were able to show that: - 1 Below a critical molecular weight of about 2·104, the linear correlation dn/dc=f(1/Mn) is well explained by the influence of chemical heterogeneities included in the polymer chain (end-groups, branching points etc.).
- 2 These rules do not account for specific polymer-solvent interactions and are not quite rigorous.
- 3 The variations of (dn/dc) and the partial specific volume of the polymer, v?p, observed already for molecular weights higher than 2·104 are accompagnied by a change in the partial specific refractivity. These effects are related to the influence of intramolecular segment density in the interior of the linear or branched coil.
A homologous series of polyoxyethylene-glycols (α-hydro-ω-hydroxypoly(oxyethylene)s) in benzene presents the same behaviour. |
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