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吉林人参花蕾的化学研究(4)——人参皂甙Ro、Rb_1、Rf、Rg_1的分离与鉴定
引用本文:邵春杰,徐景达.吉林人参花蕾的化学研究(4)——人参皂甙Ro、Rb_1、Rf、Rg_1的分离与鉴定[J].吉林大学学报(医学版),1987(5).
作者姓名:邵春杰  徐景达
作者单位:白求恩医科大学化学教研室 (邵春杰),白求恩医科大学化学教研室(徐景达)
摘    要:继前文1,2]报道从吉林人参(Panax ginseng C.A.Meyer)的花蕾中分离鉴定了七种人参皂甙(ginsenoside-Rb_2、-Rb_3、-Rc、-Rd、-Re、-Rg_2和20—glC—Rf)之后,又从中分离出五种人参皂甙(甙Ⅷ—Ⅻ)。通过测定其理化常数、IR、′H—NMR、~3C—NMR、EI—MS、FD—MS,制备衍生物,并与标准品对照鉴定了其中四种,甙Ⅷ、~1Ⅸ、Ⅸ、Ⅻ分别为ginsenoside-Ro、-Rb_1、-Rf和-Rg_1,另一种在鉴定中。ginsenoside-Ro(Ⅷ)和-Rf(Ⅻ)从人参花蕾中分离鉴定为首次报道。

关 键 词:人参花蕾  人参皂甙-Ro、-Rb、-Rf、-Rg、-Rf分离鉴定

Study on constituents of flower - buds of Panax ginseng C.A.Meyer (Ⅳ) isolatjon and identifcation of another 5 ginsenosides
Shao Chunjie and Xu Jingda.Study on constituents of flower - buds of Panax ginseng C.A.Meyer (Ⅳ) isolatjon and identifcation of another 5 ginsenosides[J].Journal of Jilin University: Med Ed,1987(5).
Authors:Shao Chunjie and Xu Jingda
Institution:Shao Chunjie and Xu Jingda
Abstract:Isolation of 7 glycosides from the flower-buds of Panax ginseng C.A. Meyer in Jilin, named as ginsenoside-Rb2, -Rb3,-Re, -Rd,-Re, -Rg2 and 20-glc-Rf was reported previously.In this paper, five other glycosides (Ⅷ, Ⅸ,Ⅹ ,Ⅺ ,Ⅻ ) were isolated.Four of these were identified to be ginsenoside -Ro(Ⅷ), -Rbl(Ⅸ), -Rgl(Ⅺ)and - Rf(Ⅻ)on basis of chemical reactions and special analyses.Identification of the fifth(Ⅹ)has not finished yet, Ginsenoside -Ro(ⅩⅢ) and -Rf(Ⅻ) were isolated and identified for the first time.
Keywords:Flower-buds of Panax ginseng C  A  Meyer Ginsenoside -Ro Ginsenoside-Rb1 Ginsenoside-Rg1 Ginsenoside-Rf Isolation and identification
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