Investigation on Naphthalene and Its Derivatives‐Based Microporous Organic Hyper‐Cross‐Linked Polymers via Different Methodologies

A series of cost‐effective hyper‐cross‐linked polymers (HCLPs) are synthesized from naphthalene via the external cross‐linker (ECL) knitting method, the solvent knitting method, and the Scholl coupling reaction, respectively. According to multiple characterizations, the resulting polymers are thermally stable and fluorescent with large specific surface areas (SSAs) and narrow pore distributions. In particular the HCLP synthesized using dimethoxymethane as the ECL exhibits SSAs up to 2870 m² g^?1 and shows a great potential in gas adsorption applications. Naphthol and 1‐methylnaphthalene are used as monomers to synthesize HCLPs by the above three methods to investigate whether introducing functional groups to naphthalene would improve properties of the resulting polymers. Moreover, HCLPs feature high SSAs, outstanding thermal and fluorescent performances, and facile synthesis, making them promising candidates for industrial applications.