Design principles for self-assembly with short-range interactions |
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Authors: | Hormoz Sahand Brenner Michael P |
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Affiliation: | School of Engineering and Applied Sciences and Kavli Institute for Bionano Science and Technology, Harvard University, Cambridge, MA 02138, USA.hormoz@fas.harvard.edu |
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Abstract: | Recent experimental advances have opened up the possibility of equilibrium self-assembly of functionalized nanoblocks with a high degree of controllable specific interactions. Here, we propose design principles for selecting the short-range interactions between self-assembling components to maximize yield. We illustrate the approach with an example from colloidal engineering. We construct an optimal set of local interactions for eight colloidal particles (coated, e.g., with DNA strands) to assemble into a particular polytetrahedral cluster. Maximum yield is attained when the interactions between the colloids follow the design rules: All energetically favorable interactions have the same strength, as do all unfavorable ones, and the number of components and energies fall within the proposed range. In general, it might be necessary to use more component than strictly required for enforcing the ground state configuration. The results motivate design strategies for engineering components that can reliably self-assemble. |
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Keywords: | programmable matter random energy model colloidal clusters directed assembly |
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