| 湖北贝母化学成分的研究 Ⅴ、湖贝新的分离和鉴定 |
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| 引用本文： | 吴继洲,王永耀,凌大奎. 湖北贝母化学成分的研究 Ⅴ、湖贝新的分离和鉴定[J]. 药学学报, 1986, 21(7): 546-550 |
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| 作者姓名： | 吴继洲 王永耀 凌大奎 |
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| 作者单位： | *湖北省药品检验所,武汉;*同济医科大学药学系;**湖北中医学院药学系,八○级毕业实习生;***卫生部药品生物制品检定所,北京 |
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| 摘 要： | A new C-nor-D-homosteroid alkaloid of 22,27-imino-17, 23-oxidojervane skeleton was isolated from the bulb of Fritillaria hupehensis Hsiao et K. C. Hsia by column chromatographic techniques, C27H41NO3, mp257～259℃, named hupehenisine.On the basis of study of the UV. IR. 1H-NMR and EI-mass spectra of hupehenisine and its diacetyl derivative, the structure of hupehenisine has been established as 22,27-imino-17,23-ozido-5α, 6-dihydrojerv-12-en-11-oxo-3β-ol (Ⅶ).
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| 关 键 词： | 贝母属 湖北贝母 浙贝甲素 浙贝乙素 湖贝甲素 湖贝甲素甙 湖贝乙素 湖贝嗪 湖贝新 22,27-亚胺-17,23-氧杰尔烷 C-去甲-D-高甾体生物碱 |
| 收稿时间： | 1985-04-24 |
STUDIES ON CHEMICAL CONSTITUENT OF HUBEIBEIMU (FRITILLARIA HUPEHENSIS HSIAO ET K. C. HSIA) V. ISOLATION AND IDENTIFICATION OF HUPEHENISINE |
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| Wu Ji-Zhou,WANG Yong-Yao and LING Da-Kui. STUDIES ON CHEMICAL CONSTITUENT OF HUBEIBEIMU (FRITILLARIA HUPEHENSIS HSIAO ET K. C. HSIA) V. ISOLATION AND IDENTIFICATION OF HUPEHENISINE[J]. Acta pharmaceutica Sinica, 1986, 21(7): 546-550 |
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| Authors: | Wu Ji-Zhou WANG Yong-Yao LING Da-Kui |
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| Affiliation: | Wu Ji-Zhou,WANG Yong-Yao~ and LING Da-Kui |
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| Abstract: | A new C-nor-D-homosteroid alkaloid of 22,27-imino-17, 23-oxidojervane skeleton was isolated from the bulb of Fritillaria hupehensis Hsiao et K. C. Hsia by column chromatographic techniques, C27H41NO3, mp257～259℃, named hupehenisine.On the basis of study of the UV. IR. 1H-NMR and EI-mass spectra of hupehenisine and its diacetyl derivative, the structure of hupehenisine has been established as 22,27-imino-17,23-ozido-5α, 6-dihydrojerv-12-en-11-oxo-3β-ol (Ⅶ). |
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| Keywords: | Hubeibeimu Peimine Peiminine Hupehenine Hupeheninoside Hupehenirine Hupehenizine Hupehenisine 22,27-imino-17, 23-oxidojervane Cnor-D-homosteroid alkaloid Fritillaria |
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