| 水溶性大分子汞离子荧光-比色探针RhBH-P(VP-co-GMA)的合成与性能 |
| |
| 引用本文： | 姜思思,苟超,吴海强,王宝清,罗静,刘晓亚. 水溶性大分子汞离子荧光-比色探针RhBH-P(VP-co-GMA)的合成与性能[J]. 医学教育探索, 2011, 24(4) |
| |
| 作者姓名： | 姜思思 苟超 吴海强 王宝清 罗静 刘晓亚 |
| |
| 作者单位： | 江南大学化工与材料工程学院，江苏 无锡 214122;江南大学化工与材料工程学院，江苏 无锡 214123;江南大学化工与材料工程学院，江苏 无锡 214124;江南大学化工与材料工程学院，江苏 无锡 214125;江南大学化工与材料工程学院，江苏 无锡 214126;江南大学化工与材料工程学院，江苏 无锡 214127 |
| |
| 基金项目： | 国家自然科学基金（20704017）； 教育部中央高校自主科研计划青年基金（JUSRP11108） |
| |
| 摘 要： | 采用活性基团修饰法，通过罗丹明B酰肼(RhBH)与乙烯基吡咯烷酮-甲基丙烯酸缩水甘油酯共聚物（P(VP-co-GMA)）侧链上环氧基团的开环反应，制得一种键合有罗丹明B酰肼的水溶性聚合物RhBH-P(VP-co-GMA)。在水溶液中，该聚合物本身无色且无荧光，加入汞离子后，罗丹明的螺环结构打开，出现显著的荧光增强和颜色变红，实现了在水溶液中对汞离子的“关开”荧光检测和裸眼检测。在此条件下，其他共存离子没有明显响应。研究表明：该聚合物是一种高选择性的Hg2+探针,可以实现水溶液中的汞离子检测。
|
| 关 键 词： | 汞离子；罗丹明B酰肼；荧光比色探针；水溶性聚合物 |
Synthesis and Photophysical Behaviors of Water Soluble Copolymer as Chemosensor for Hg2+ in Aqueous Solution |
| |
| JIANG Si-si,GOU Chao,WU Hai-qiang,WANG Bao-qing,LUO Jing and LIU Xiao-ya. Synthesis and Photophysical Behaviors of Water Soluble Copolymer as Chemosensor for Hg2+ in Aqueous Solution[J]. Researches in Medical Education, 2011, 24(4) |
| |
| Authors: | JIANG Si-si GOU Chao WU Hai-qiang WANG Bao-qing LUO Jing LIU Xiao-ya |
| |
| Affiliation: | School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China;School of Chemical and Material Engineering, Jiangnan University, Wuxi 214123, Jiangsu, China;School of Chemical and Material Engineering, Jiangnan University, Wuxi 214124, Jiangsu, China;School of Chemical and Material Engineering, Jiangnan University, Wuxi 214125, Jiangsu, China;School of Chemical and Material Engineering, Jiangnan University, Wuxi 214126, Jiangsu, China;School of Chemical and Material Engineering, Jiangnan University, Wuxi 214127, Jiangsu, China |
| |
| Abstract: | A novel water soluble copolymer RhBH-P(VP-co-GMA) bearing rhodamine B hydrazine (RhBH) was prepared by ring opening reaction between RhBH and a water soluble copolymer P(VP co GMA) which was synthesized by radical polymerization of N-vinyl pyrolidone (VP) and glycidyl methacrylate (GMA). Upon addition of Hg2+, the spirocyclic ring of RhBH-P(VP-co- GMA) was opened and a significant fluorescence enhancement as well as colorimetric change was observed, which allowed to detect Hg2+ in aqueous solution by both fluorescence technique and naked eye. In addition, the feeding of other transition metal ions has no interference, which shows RhBH-P(VP-co-GMA) is a highly selective macromolecular probe for detection of Hg2+ in aqueous solution. |
| |
| Keywords: | mercury ion rhodamine B hydrazine fluorescence and colorimetric probe water soluble polymer |
|
| 点击此处可从《医学教育探索》浏览原始摘要信息 |
|
点击此处可从《医学教育探索》下载全文 |
|
