Polymerisation von fulvenen, 3. Strukturbeweis für kationische polyfulvene durch vergleich mit modellverbindungen |
| |
| Authors: | Stefan Sch nholzer,Mario Slongo,Christoph Rentsch,Markus Neuenschwander |
| |
| Affiliation: | Stefan Schönholzer,Mario Slongo,Christoph Rentsch,Markus Neuenschwander |
| |
| Abstract: | The structure of cationic poly(6,6-dimethylfulvene) ( 2a ) has been confirmed by synthesis of 4 model compounds 6, 7, 8, 9 and comparison of the spectral data with those of the polyfulvene. 5-Isoproylidenetricyclo[5.2.1.02.6]dec-3-ene ( 6 ) shows the same sensitivity towards oxygen as 2a . The reaction of 6 with oxygen yields a 1:1-copolymer, for which structure 10 has been proved by means of spectroscopic methods. |
| |
| Keywords: | |
|
|
