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Flexible Sol-Gel—Processed Y2O3 RRAM Devices Obtained via UV/Ozone-Assisted Photochemical Annealing Process
Authors:Hyeon-Joong Kim  Do-Won Kim  Won-Yong Lee  Kyoungdu Kim  Sin-Hyung Lee  Jin-Hyuk Bae  In-Man Kang  Kwangeun Kim  Jaewon Jang
Institution:1.School of Electronic and Electrical Engineering, Kyungpook National University, Daegu 41566, Korea; (H.-J.K.); (D.-W.K.); (W.-Y.L.); (K.K.); (S.-H.L.); (J.-H.B.); (I.-M.K.);2.School of Electronics Engineering, Kyungpook National University, Daegu 41566, Korea;3.School of Electronics and Information Engineering, Korea Aerospace University, Goyang 10540, Korea;
Abstract:Flexible indium tin oxide (ITO)/Y2O3/Ag resistive random access memory (RRAM) devices were successfully fabricated using a thermal-energy-free ultraviolet (UV)/ozone-assisted photochemical annealing process. Using the UV/ozone-assisted photochemical process, the organic residue can be eliminated, and thinner and smother Y2O3 films than those formed using other methods can be fabricated. The flexible UV/ozone-assisted photochemical annealing process-based ITO/Y2O3/Ag RRAM devices exhibited the properties of conventional bipolar RRAM without any forming process. Furthermore, the pure and amorphous-phase Y2O3 films formed via this process showed a decreased leakage current and an increased high-resistance status (HRS) compared with the films formed using other methods. Therefore, RRAM devices can be realized on plastic substrates using a thermal-energy-free UV/ozone-assisted photochemical annealing process. The fabricated devices exhibited a resistive window (ratio of HRS/low-resistance status (LRS)) of >104, with the HRS and LRS values remaining almost the same (i.e., limited deterioration occurred) for 104 s and up to 102 programming/erasing operation cycles.
Keywords:sol-gel  Y2O3  RRAM  UV/ozone  photochemical  flexible
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