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Halogen-free instinct flame-retardant waterborne polyurethanes: composition,performance, and application
Authors:Xuan Yin  Liqi Li  Haosheng Pang  Yunjun Luo  Bing Zhang
Affiliation:College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029 China ; Beijing Institute of Technology, Beijing 100081 China.; Department of Mechanical Engineering, Tsinghua University, Beijing 100084 China
Abstract:Ideal halogen-free instinct flame-retardant waterborne polyurethanes have high flame-retardant efficiency, environmental friendliness, fine compatibility, and good thermostability. Phosphorus flame-retardants are currently widely used in halogen-free instinct flame-retardant waterborne polyurethanes (HIFWPU), especially those with phosphorous–nitrogen co-structures. Phosphorous–nitrogen HIFWPU have become a hotspot because their co-structures provide higher flame-retardance as compared to waterborne polyurethanes. This review introduces three main types of HIFWPU based on composition, performance and application. HIFWPU not only have improved flame-retardance but also satisfy the various requirements for functionality. HIFWPU have been widely developed in textile, furniture, automobile, and aerospace applications.

Ideal halogen-free instinct flame-retardant waterborne polyurethanes have high flame-retardant efficiency, environmental friendliness, fine compatibility, and good thermostability.
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