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Mechanical and physical properties of silorane and methacrylate-based composites
Authors:Isabel Cristina Celerino de Moraes Porto  Flávio Henrique Baggio de Aguiar  William Cunha Brandt  Priscila Christiane Susy Liporoni
Affiliation:1. Department of Restorative Dentistry, Federal University of Alagoas, Campus AC Simões, Av. Lourival Melo Mota, S/N, Tabuleiro do Martins, CEP: 57072-970, Maceió, Alagoas, Brazil;2. Department of Restorative Dentistry, State University of Campinas, Av. Limeira, 901, Areião, CEP: 13414-903, Piracicaba, São Paulo, Brazil;3. Department of Dentistry, University of Santo Amaro, R. Prof. Eneas de Siquera Neto, 340, Cidade Dutra, CEP: 04829-300, São Paulo, São Paulo, Brazil;4. Department of Restorative Dentistry, University of Taubaté, R. dos Operários, 9, Centro, CEP: 12020-340, Taubaté, São Paulo, Brazil
Abstract:ObjectivesThis study measured the degree of conversion (DC), sorption, solubility and microhardness of methacrylate (Filtek Z250 and Filtek Z350XT) and silorane-based composites (Filtek P90).MethodsDC was measured using near infrared spectroscopy immediately and 24 h after the photoactivation. Sorption and solubility measurements were performed after 24 h, 4 weeks and 12 weeks of storage in water. Knoop microhardness was measured after 24 h and after thermal cycling. The data were statistically analyzed using ANOVA followed by Tukey's, Tamhane or paired t-tests (α = 0.05).ResultsThe DC for P90 (37.22 ± 1.46) was significantly lower than the Z250 (71.44 ± 1.66) and Z350 (71.76 ± 2.84). Water sorption was highest in the Z250 and lowest in the P90. All the tested composites exhibited similar values after 24 h of immersion, and no significant differences were observed. No significant differences were observed between the solubilities of the P90 composite (12 weeks) and the Z250 or Z350 composites (4 weeks). KHN values were less elevated for the P90 composite and similar for the Z250 and Z350 composites. An effect of thermal cycling on KHN values was observed for all the composites (p < 0.001).ConclusionsSilorane produced the lowest DC and KHN values and exhibited lower water sorption and solubility compared to methacrylate-based composites. These differences suggest that silorane composites exhibit better hydrolytic stability after 3 months of water immersion compared to conventional methacrylate-based composites.Clinical significanceSilorane had higher hydrolytic stability after 3 months of water immersion than the methacrylate-based resins, despite the lower values of DC and KHN recorded.
Keywords:Composites  Hardness tests  Degree of conversion  Sorption  Solubility
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