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Decoration of Zinc Oxide Nanorods into the Surface of Activated Carbon Obtained from Agricultural Waste for Effective Removal of Methylene Blue Dye
Authors:Priyanka Shrestha  Manoj Kumar Jha  Jeevan Ghimire  Agni Raj Koirala  Rajeshwar Man Shrestha  Ram Kumar Sharma  Bishweshwar Pant  Mira Park  Hem Raj Pant
Institution:1.Nanomaterials Lab, Department of Applied Sciences and Chemical Engineering, Pulchowk Campus, Institute of Engineering, Tribhuvan University, Kathmandu 44600, Nepal; (P.S.); (M.K.J.); (J.G.); (R.M.S.); (R.K.S.);2.Korea Center for Artificial Photosynthesis, Department of Chemistry, Sogang University, Shinsu-dong, Mapo-go, Seoul 121-742, Korea;3.Carbon Composite Energy Nanomaterials Research Center, Woosuk University, Wanju-Gun, Jeollabuk-do 55338, Korea
Abstract:Zinc oxide (ZnO) nanorods incorporated activated carbon (AC) composite photocatalyst was synthesized using a hydrothermal process. The AC was prepared from lapsi (Choerospondias axillaris) seed stone, an agricultural waste product, found in Nepal by the chemical activation method. An aqueous suspension of AC with ZnO precursor was subjected to the hydrothermal treatment at 140 °C for 2 h to decorate ZnO rods into the surface of AC. As-obtained ZnO nanorods decorated activated carbon (ZnO/AC) photocatalyst was characterized by various techniques, such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and photoluminescence (PL) spectroscopy. Results showed that highly crystalline hexagonal ZnO nanorods were effectively grown on the surface of porous AC. The photocatalytic property of the as-prepared ZnO/AC composite was studied by degrading methylene blue (MB) dye under UV-light irradiation. The ZnO/AC composite showed better photocatalytic property than that of the pristine ZnO nanorods. The enhanced photocatalytic performance in the case of the ZnO/AC composite is attributed to the combined effects of ZnO nanorods and AC.
Keywords:ZnO nanorods  activated carbon  composite  hydrothermal  photocatalyst
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