Institute of Organic Chemistry, University of Mainz, Duesbergweg 10–14, 55099 Mainz, Germany
Abstract:
The polycondensation of trialkoxysilanes to PSSQs in a microreactor setup is demonstrated. While continuous‐flow processes involving microreactors found various applications in chain growth polymerization, their influence on step‐growth polymerization is less explored, and the polycondensation of multifunctional monomers has not been studied in detail. We found significantly increased yields and a decreased polydispersity of the obtained polymers in comparison to the batch process. By variation of the residence time molecular weights could be adjusted reproducibly ranging from = 1 900 to 11 000 g · mol?1. Thus, the microreactor setup offers for the first time the possibility to synthesize PSSQ with adjustable properties.