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镍铬、钴铬合金和纯钛在人工唾液中的耐腐蚀性评价
引用本文:陆春慧,郑元俐,邱憬.镍铬、钴铬合金和纯钛在人工唾液中的耐腐蚀性评价[J].上海口腔医学,2010,19(2).
作者姓名:陆春慧  郑元俐  邱憬
作者单位:上海交通大学医学院附属第九人民医院·口腔医学院,口腔修复科;上海市口腔医学重点实验室,上海,200011
基金项目:上海市科学技术委员会资助项目(08DZ2271100); 上海市重点学科建设项目(T0202)~~
摘    要:目的:用电化学交流阻抗谱方法研究钴铬、镍铬合金和纯钛在人工唾液中的耐腐蚀性。方法:用电化学工作站测量出3种金属材料在人工唾液中的电化学阻抗谱(Bode图、Nyquist图),利用ZSimpWin软件对数据进行拟合分析,根据等效电路R(CR)拟合结果来评估3种金属的耐腐蚀性能。结果:从Nyquist图可见,3种材料的容抗弧半径大小依次为纯钛>钴铬合金>镍铬合金;从Bode图见,3种材料均为一个时间常数,即表面均是一个电容层。根据等效电路R(CR),3种材料的电容层无明显区别,但三者的阻抗值均很大,其中纯钛的阻抗值最大,钴铬合金的阻抗值居中,镍铬合金的阻抗值最小。结论:3种材料在人工唾液中均具有良好的耐腐蚀性,其耐腐蚀性能顺序是纯钛>钴铬合金>镍铬合金。

关 键 词:镍铬合金  钴铬合金    电化学交流阻抗谱  等效电路  耐腐蚀性  

Study of dental alloys in the artificial saliva using an electrochemical impedance spectroscopy
LU Chun-hui,ZHENG Yuan-li,QIU Jing.Study of dental alloys in the artificial saliva using an electrochemical impedance spectroscopy[J].Shanghai Journal of Stomatology,2010,19(2).
Authors:LU Chun-hui  ZHENG Yuan-li  QIU Jing
Institution:LU Chun-hui,ZHENG Yuan-li,QIU Jing. (Department of Prosthodontics,Ninth People\'s Hospital,College of Stomatology,Shanghai Jiao Tong University School of Medicine,Shanghai Key Laboratory of Stomatology. Shanghai 200011,China)
Abstract:PURPOSE:With the help of electrochemical impedance spectroscopy (EIS),the purpose of the study was to investigate the corrosion resistance of CoCr alloys ,NiCr alloys and commercially pure Ti(cp Ti) in the artificial saliva(AS). METHODS:With the EIS,a test was made on the three alloys/metals in the AS (See Bode plot and Nyquist plot). And then,an analysis was made on what was known in the test by the software of ZSimpWin,after which the corrosion resistance of the alloys/metals was evaluated against the par...
Keywords:CoCr alloy  NiCr alloy  Titanium  Electrochemical impedance spectroscopy  Equivalent circuit  Corrosion resistance  
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